Oxygen Difluoride or OF2 is a chemistry compound formed by the reaction between halogen fluorine and also dilute aqueous solution of NaOH ( salt hydroxide ).

You are watching: Give the hybridization for the o in of2.

The equation for the preparation of Oxygen Difluoride:

2F2 + 2NaOH ——> OF2 + 2NaF + H2O

It is a colorless gaseous compound exhibiting a strong peculiar odor and acts together an oxidizer. It has a boiling point of 128.40 K and also a melting suggest of 49.3 K. It has actually a molar fixed of 53.996 g/mol and a density of 1.88 g/l together a gas in ~ room temperature.

Although it has its use as a strong oxidizing agent, because that example, in propellants that rocket fuels, this property additionally makes the compound unsafe.

OF2 have the right to explode on call with water and is said to be highly corrosive come the skin. It have the right to also affect the eyes and the cardiovascular system.

Let us have actually a quick however detailed look into the within of the molecule and discuss the nature of chemistry bonding.

OF2 Lewis Structure

Do you recognize that several determinants make atom come together and combine to type several various chemical compounds?

When atom come together and also create bonds, a brand-new molecule is created.

Usually, the electron in the outermost shell of an atom, also known together valence electrons, take component in chemistry bonding.

Lewis Structure, thus, is a basic and constructive procedure to sketch a diagrammatic depiction of a molecule v the help of electron-dot structures.

It provides us a 2D figure and helps us have a brief idea about the electron arrangement and the kind of bond development without walk much right into detail.

Now, us will talk about the steps to type the Lewis framework of OF2.

Steps to kind OF2 Lewis structure Diagram

Step 1: Find the Total variety of Valence Electrons.

The first and foremost action is to calculate the total variety of valence electron in one OF2 molecule.

Oxygen belonging to group 16, the chalcogen family, and also has a valency the 6. Fluorine belongs to the family members of halogen in team 17 and has a valency that 7.

Therefore, the total number of valence electrons = 6 + 7*2 = 20.

Step 2: Identify the central Atom

Now, we have to decipher the central atom in this molecule. If us look in ~ the Pauling Electronegativity chart, us can find out that the least electronegative element among oxygen and fluorine is Oxygen (O).


The central atom in one oxygen difluoride molecule is Oxygen.

Step 3: Sketch the skeletal Diagram of the Molecule

In Lewis Structure, we use atomic symbols prefer C for carbon, H because that hydrogen to stand for the ingredient atoms, and also electron dot notation to stand for the valence covering electrons.

Let us look in ~ the listed below skeletal sketch:

The atomic symbols:


Atomic symbols along with dot notations:


Step 4: Octet rule 

The key group facets ( team 1 to team 17 ) that the regular table have actually a propensity to acquire the octet configuration of the noble gas elements present in team 18 that the exact same period. This is recognized as octet fulfillment since the facets want to achieve eight electrons in your valence shells.

For example, Carbon tends to achieve a Neon configuration.

Exception: Hydrogen tends to accomplish Helium configuration, hence only two electrons in the outer shell.

Here, if us look in ~ the octet rule, both the fluorine atoms have completed a valency that eight. The exact same goes for the central oxygen atom.

Step 5: Formal charge Concept

Before we continue to confirm any type of sketch to be the perfect Lewis framework for a given molecule or ionic structure, we need to examine the formal charge values.


For Oxygen: Formal fee = 6 – 0.5*4 – 4 = 6 – 2 – 4 = 0.

For each Fluorine atom: Formal charge = 7 – 0.5*2 – 6 = 7 – 1 -6 = 0.

Since the aspects are existing in their least feasible formal fee values, we have accomplished our an ideal Lewis structure configuration.

Let united state see:


Here, oxygen develops a solitary bond v each of the fluorine atom (O-F).

OF2 molecule Geometry

We have already found the 2D Lewis framework diagram of the Oxygen Difluoride molecule.

Now, we room going to decipher the 3D molecule shape. Via Lewis Structure, we have actually realized the type of link formed and the number of lone or unbonded bag of valence electrons existing in one OF2 molecule.

Our following step is to usage Valence covering Electron Pair Repulsion concept (VSEPR) to uncover the specific molecular geometry in addition to the shortcut angles.

Like charged electrons create a negatively fee cloud neighboring the atom nuclei and also repulsion is created. The VSEPR design tends to mitigate or minimization the repulsive forces and balance the security of any type of given molecule, in this case, OF2.

Let us look in ~ this VSEPR chart mirroring AXN notations:


According to AXnEx notation that VSEPR theory,

A: central atom ( Oxygen )

X: no. Of surrounding atoms, ‘n’ = 2 ( Fluorine )

E: no. Of lone bag of electrons of the main atom, ‘X = 2.

The VSEPR notation because that the OF2 molecule is AX2E2. According to the over chart, we have actually a bend molecule structure.

The bond angle is about 103 levels (due come the repulsion of the lone pair).



In chemistry, an orbit is a resolved path approximately the nucleus in i beg your pardon electrons often tend to relocate or revolve. One orbital, on the other hand, is identified to it is in the probability that the existence of one electron in any type of given regional space.

Atomic orbitals room of number of shapes prefer spherical, dumb-bell, clover-leaf, or doughnut to name a few of the complicated varieties. We have actually s,p,d,f atomic orbitals ( AOs ).

Electrons can be explained via their wave features in quantum mechanics. If us take right into account the mix of wave attributes of number of atomic orbitals, us come throughout the procedure of hybridization.

For example, the wave attributes of the s and also a 2px orbitals offer rise come sp hybridization which usually outcomes in a direct geometry.

Hybridization in OF2

Let united state look at the digital configuration the oxygen and also fluorine in your ground states.

O: 1s2 2s2 2p4

F: 1s2 2s2 2p5


After creating bonds with halogen F and attaining octet configuration, the electronic structure of O looks like this:


We, therefore, have in the outermost covering of the central oxygen atom, four hybridized orbitals: 2s, 2px, 2py, 2pz.

Steric number = variety of atoms external inspection to central atom within a molecule + number of lone pair of electron attached to the central atom

Also, steric number = 2 + 2 = 4.

Therefore, we have sp3 hybridization for the central oxygen atom in a molecule the oxygen difluoride ( OF2 ).

OF2 Polarity

Let us know at an initial what we median by the really famous and common terminology: Polarity.

Polarity can be defined as the physical residential property of any kind of molecule or chemistry compound where the constituent atomic aspects can possess either optimistic or an adverse charges or both.

We have already seen the Pauling Electronegativity chart. Each and also every element of the main teams in the regular table has a specific value the electronegativity.

When atom of the same element come together in equal ratio, the charge worths neutralize themselves and also the net dipole is zero, thus the molecule is non-polar. Direct or symmetrical chemical molecules room usually non-polar. ( e.g. : H2 )

However, if molecules consist the uneven partial fee distributions as result of a difference in electronegativity or the molecular form is asymmetrical, the network dipole no cancel or i do not care zero and also we have a polar molecule.( e.g. : H3PO4, HCl ).

You can additionally refer to the polarity the HCl.

Is OF2 a polar molecule?

Let us have actually a fast look right into the molecular form of Oxygen Difluoride. The is almost similar to H2O and in both cases, the central O has two lone pairs on the top.

The electronegativity value of Oxygen is 3.44. And, that of fluorine is 3.98.

Since oxygen is much more electropositive 보다 fluorine atoms, it will possess a partial optimistic charge ( δ+ ) and each that the F atoms will certainly possess a an unfavorable partial charge ( δ- ).

So, we can see that there is one electronegativity difference and also henceforth the net dipole moment is no equal to zero.

Again, OF2 is not a symmetrical direct structure. The lone bag on the central Oxygen atom provide it a bending molecule geometry which resembles the English letter V.

We have actually gone with both the uneven fee distribution and the asymmetry that Oxygen Difluoride.The molecule is polar in nature.

For thorough information, girlfriend must also read the end the write-up written around the polarity the OF2.

OF2 Molecular orbital (MO) Diagram

Valence Bond concept is essential for explaining chemistry bonding within a molecule structure however it has actually several constraints or drawbacks.

Here, come the molecular Orbital theory or MOT.

In MOT, us take into account the ide of molecular orbitals (MOs) which are orbitals that the molecule as a whole and also not just those the constituent separation, personal, instance atoms.

It considers electrons to be delocalized and also results in developing bonding and anti-bonding interactions in orbitals.

To showcase the relative power levels that the AOs and also the resultant MOs, we have the Molecular orbital diagrams.

The lower energy molecular orbit is the bonding and also the greater energy is the anti-bonding orbital.

The below-mentioned diagram provides us the separation, personal, instance MO diagrams the Oxygen and also Fluorine separately, the atoms that consist of a molecule of OF2.



In this article, we have disputed the type of chemical bonding occurring inside one OF2 molecule. Oxygen Difluoride is an interesting molecule the was found accidentally and also later had several applications although that was toxic in nature.

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We have covered Lewis Structure, VSEPR concept to recognize molecular geometry, Hybridization, Polar nature, and also a short discussion ~ above MO diagram around oxygen difluoride.